Publications

2024

Anomalously enhanced ion transport and uptake in functionalized angstrom-scale two-dimensional channels, Mingzhan Wang, Tumpa Sadhukhan, Nicholas H. C. Lewis, Maoyu Wang, Xiang He, Gangbin Yan, Dongchen Ying, Eli Hoenig, Yu Han, Guiming Peng, One-Sun Lee, Fengyuan Shi, David M. Tiede, Hua Zhou, Andrei Tokmakoff, George C. Schatz and Chong Liu, Proc. Natl. Acad. Sci. U. S. A. 121, e2313616121, (2024).

2023

Strong H-bonding from Zeolite Bronsted Acid Site to Water: Origin of the Broad IR Doublet, John H. Hack, Yaxin Chen, Nicholas H. C. Lewis, Harold H. Kung and Andrei Tokmakoff, J. Phys. Chem. B 127, 11054-11063, (2023).

Vibrational Probe at the Electrochemical Interface: Dependence on Plasmon Coupling and Potential of the Lineshape in Two-Dimensional Infrared Spectroscopy, Melissa Bodine, Vepa Rozyyev, Jeffrey W. Elam, Andrei Tokmakoff and Nicholas H. C. Lewis, J. Phys. Chem. Lett. 14, 11092–11099, (2023).

Development and Characterization of Electrodes for Surface-Specific Attenuated Total Reflection Two-Dimensional Infrared Spectroelectrochemistry, Melissa Bodine, Vepa Rozyyev, Jeffrey W. Elam, Andrei Tokmakoff and Nicholas H. C. Lewis, J. Phys. Chem. C 127, 23199–23211 (2023).

Proton Dissociation and Delocalization under Stepwise Hydration of Zeolite HZSM-5, John H. Hack, Xinyou Ma, Yaxin Chen, James P. Dombrowski, Nicholas H. C. Lewis, Chenghan Li, Harold H. Kung, Gregory A. Voth, and Andrei Tokmakoff, J. Phys. Chem. C 127, 16175-16186 (2023).

Amplification of mid-IR continuum for broadband 2D IR spectroscopy, John H. Hack, Nicholas H. C. Lewis, William B. Carpenter, and Andrei Tokmakoff, Opt. Lett. 44, 1003 (2023).

2022

From Networked to Isolated: Observing Water Hydrogen Bonds in Concentrated Electrolytes with Two–Dimensional Infrared Spectroscopy, Nicholas H. C. Lewis, Bogdan Dereka Yong Zhang, Edward J. Maginn, and Andrei Tokmakoff, J. Phys. Chem. B. 126, 5305-5319 (2022).

Exchange–Mediated Transport in Battery Electrolytes: Ultrafast or Ultraslow, Bogdan Dereka, Nicholas H. C. Lewis, Jonathan H. Keim,  Scott A. Snyder, Edward Maginn, and Andrei Tokmakoff, J. Am. Chem. Soc. 144, 8591-8604 (2022).

Characterization of Acetonitrile Isotopologues as Vibrational Probes of Electrolytes, Bogdan Dereka, Nicholas H. C. Lewis, Jonathan H. Keim,  Scott A. Snyder, and Andrei Tokmakoff, J. Phys. Chem. B 126, 278-291 (2022).

2021

Lineshape Distortions in Internal Reflection Two-Dimensional Infrared Spectroscopy: Tuning across the Critical Angle, Nicholas H. C. Lewis, and Andrei Tokmakoff, J. Phys. Chem. Lett. 12, 11843–11849 (2021).

Water or Anion? Uncovering the Zn2+ Solvation Environment in Mixed Zn(TFSI)2 and LiTFSI Water-in-Salt Electrolytes, Yong Zhang, Gang Wan, Nicholas H. C. Lewis, Julian Mars, Sharon E. Bone, Hans-Georg Steinrück, Maria R. Lukatskaya, Nicholas J. Weadock, Michal Bajdich, Oleg Borodin, Andrei Tokmakoff, Michael F. Toney, and Edward J. Maginn,  ACS. Energy. Lett. 6, 3458–3463 (2021).

Advanced Materials for Energy-Water Systems: The Central Role of Water/Solid Interfaces in Adsorption, Reactivity, and Transport, Edward Barry, Raelyn Burns, Wei Chen, Guilhem X. De Hoe, Barry, Joan Manuel Montes De Oca, Juan J. de Pablo, James Dombrowski, Jeffrey W. Elam, Alanna M. Felts, Giulia Galli, John Hack, Qiming He, Xiang He, Eli Hoenig, Aysenur Iscen, Benjamin Kash, Harold H. Kung, Nicholas H. C. Lewis, Chong Liu, Xinyou Ma, Anil Mane, Alex B. F. Martinson, Karen L. Mulfort, Julia Murphy, Kristian Mølhave, Paul Nealey, Yijun Qiao, Vepa Rozyyev, George C. Schatz, Steven J. Sibener, Dmitri Talapin, David M. Tiede, Matthew V. Tirrell, Andrei Tokmakoff, Gregory A. Voth, Zhongyang Wang, Zifan Ye, Murat Yesibolati, Nestor J. Zaluzec, Seth B Darling., Chem. Rev. 121, 9450–9501 (2021).

Structural Characterization of Protonated Water Clusters Confined in HZSM-5 Zeolites, John H. Hack, James P. Dombrowski, Xinyou Ma, Yaxin Chen, Nicholas H. C. Lewis, William B. Carpenter, Chenghan Li, Gregory A. Voth, Harold H. Kung, and Andrei Tokmakoff, J. Am. Chem. Soc. 143, 10203–10213 (2021).

Water-in-Salt LiTFSI Aqueous Electrolytes. 1. Liquid Structure from Combined Molecular Dynamics Simulation and Experimental Studies, Yong Zhang, Nicholas H. C. Lewis, Julian Mars, Gang Wan, Nichloas J. Weadock, Christopher J. Takacs, Maria R. Lukatskaya, Hans-Georg Steinrück, Michael F. Toney, Andrei Tokmakoff, and Edward J. Maginn, J. Phys. Chem. B 125, 4501–4513 (2021).

Crossover from hydrogen bonding to chemical bonding, Bogdan Dereka, Qi Yu, Nicholas H. C. Lewis, William B. Carpenter, Joel M. Bowman, Andrei Tokmakoff, Science 371, 160-164 (2021).

2020

Temperature-Jump 2D IR Spectroscopy with Intensity-Modulated CW Optical Heating, Brennan Ashwood, Nicholas H.C. Lewis, Paul J. Sanstead, and Andrei Tokmakoff, J. Phys. Chem. B 124, 8665-8677 (2020).

Vibrational Probe of Aqueous Electrolytes: The Field Is Not Enough, Nicholas H. C. Lewis, Aysenur Iscen, Alanna Felts, Bogdan Dereka, George C. Schatz, and Andrei Tokmakoff, J. Phys. Chem. B 124, 7013-7026 (2020).

Signatures of Ion-Pairing and Aggregation in the Vibrational Spectroscopy of Super-Concentrated Aqueous Lithium Bistriflimide Solutions, Nicholas H.C. Lewis, Yong Zhang, Bogdan Dereka, Emily V. Carino, Edward J. Maginn, and Andrei Tokmakoff, J. Phys. Chem. C 124, 3470-3481 (2020).

2019

High-Level VSCF/VCI Calculations Decode the Vibrational Spectrum of the Aqueous Proton, Qi Yu, William B. Carpenter, Nicholas H. C. Lewis, Andrei Tokmakoff, and Joel M. Bowman, J. Phys. Chem. B 123, 7214-7224 (2019).

Entropic barriers in the kinetics of aqueous proton transfer, William B. Carpenter, Nicholas H. C. Lewis, Joseph A. Fournier, and Andrei Tokmakoff, J. Chem. Phys. 151, 034501 (2019).

Two-dimensional electronic vibrational spectroscopy and ultrafast excitonic and vibronic photosynthetic energy transfer, Eric C. Wu, Eric A. Arsenault, Pallavi Bhattacharyya, Nicholas H. C. Lewis, and Graham R. Fleming, Faraday Discuss. 216, 116 (2019).

Two-Dimensional Electronic Vibrational Spectroscopy, Graham R. Fleming, Nicholas H. C. Lewis, Eric A. Arsenault, Eric C. Wu, and S. OldemeyerIn: Coherent Multidimensional Spectroscopy. Springer Series in Optical Sciences, vol 226. (2019).

Two-dimensional electronic-vibrational spectroscopic study of conical intersection dynamics: an experimental and electronic structure study, Eric C. Wu, Qinghui Ge, Eric A. Arsenault, Nicholas H. C. Lewis, Natalie L. Gruenke, Martin J. Head-Gordon, and Graham R. Fleming, Phys. Chem. Chem. Phys., 21, 14153, (2019).

Direct Observation of Ion Pairing in Aqueous Nitric Acid Using 2D Infrared Spectroscopy, Nicholas H. C. Lewis, Joseph A. Fournier, William B. Carpenter, and Andrei Tokmakoff, J. Phys. Chem. B 123, 225-238 (2019).

2018

Broadband 2D IR spectroscopy reveals dominant asymmetric H5O2+ proton hydration structures in acid solutions, Joseph A. Fournier, William B. Carpenter, Nicholas H.C. Lewis, and Andrei Tokmakoff, Nat. Chem. 10, 932-937 (2018).

Picosecond Proton Transfer Kinetics in Water Revealed with Ultrafast IR Spectroscopy, William B. Carpenter, Joseph A. Fournier, Nicholas H.C. Lewis, and Andrei Tokmakoff, J. Phys. Chem. B 122, 2792-2802 (2018).

2016

Observation of electronic excitation transfer through Light Harvesting Complex II using two-dimensional electronic–vibrational spectroscopy, Nicholas H. C. Lewis, Natalie L. Gruenke, Thomas A. A. Oliver, Matteo Ballottari, Roberto Bassi, and Graham R. FlemingJ. Phys. Chem. Lett., 7, 41974206 (2016).

Two-Dimensional Electronic-Vibrational Spectroscopy of Chlorophyll a and b, Nicholas H. C. Lewis, and Graham R. FlemingJ. Phys. Chem. Lett., 7, 831-837 (2016).

2015

A method for the direct measurement of electronic site populations in a molecular aggregate using two-dimensional electronic-vibrational spectroscopy, Nicholas H. C. Lewis, Hui Dong, Thomas A. A. Oliver, and Graham R. Fleming, J. Chem. Phys., 143, 124203 (2015).

Measuring correlated electronic and vibrational spectral dynamics using line shapes in two-dimensional electronic-vibrational spectroscopy, Nicholas H. C. Lewis, Hui Dong, Thomas A. A. Oliver, and Graham R. Fleming, J. Chem. Phys., 142, 174202 (2015).

Determining the static electronic and vibrational energy correlations via two-dimensional electronic-vibrational spectroscopy, Hui Dong, Nicholas H. C. Lewis, Thomas A. A. Oliver, and Graham R. Fleming, J. Chem. Phys., 142, 174201 (2015).

2014

Correlating the motion of electrons and nuclei with two-dimensional electronic-vibrational spectroscopy, Thomas A. A. Oliver, Nicholas H. C. Lewis, and Graham R. Fleming, Proc. Natl. Acad. Sci. U. S. A., 111, 1006110066 (2014).

2012

Signatures of correlated excitonic dynamics in two-dimensional spectroscopy of the Fenna-Matthew-Olson photosynthetic complex, Justin R. Caram, Nicholas H. C. Lewis, Andre F. Fidler, and Gregory S. Engel, J. Chem. Phys., 136, 104505 (2012).

2011

Direct evidence of quantum transport in photosynthetic light-harvesting complexes, Gitt Panitchayangkoon, Dmitir V. Voronine, Darius Abramavicius, Justin R. Caram, Nicholas H. C. Lewis, Shaul Mukamel, and Gregory S. Engel, Proc. Natl. Acad. Sci. U. S. A., 108, 20908-20912 (2011).

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